Nomenclature of Heterocyclic Compounds | Super-Concept & Tricks | Explained by IITian | Jee | NEET Video
Hello Guys, Today we are going to discuss a very important topic for JEE, NEET, BITSAT ,AIIMS and many others competitive examination.
Yes, It is naming of Heterocyclic Compounds.
Compounds classified as heterocyclic probably constitute the largest and most varied family of organic compounds. After all, every carbocyclic compound, regardless of structure and functionality, may in principle be converted into a collection of heterocyclic analogs by replacing one or more of the ring carbon atoms with a different element. Even if we restrict our consideration to oxygen, nitrogen and sulfur (the most common heterocyclic elements), the permutations and combinations of such a replacement are numerous.
Devising a systematic nomenclature system for heterocyclic compounds presented a formidable challenge, which has not been uniformly concluded. Many heterocycles, especially amines, were identified early on, and received trivial names which are still preferred. Some monocyclic compounds of this kind are shown in the following chart, with the common (trivial) name in bold and a systematic name based on the Hantzsch-Widman system given beneath it in blue. The rules for using this system will be given later. For most students, learning these common names will provide an adequate nomenclature background.
The Hantzsch-Widman system provides a more systematic method of naming heterocyclic compounds that is not dependent on prior carbocyclic names. It makes use of the same hetero atom prefix defined above (dropping the final "a"), followed by a suffix designating ring size and saturation. As outlined in the following table, each suffix consists of a ring size root (blue) and an ending intended to designate the degree of unsaturation in the ring. In this respect, it is important to recognize that the saturated suffix applies only to completely saturated ring systems, and the unsaturated suffix applies to rings incorporating the maximum number of non-cumulated double bonds. Systems having a lesser degree of unsaturation require an appropriate prefix, such as "dihydro"or "tetrahydro".
Despite the general systematic structure of the Hantzsch-Widman system, several exceptions and modifications have been incorporated to accommodate conflicts with prior usage. Some examples are:
• The terminal "e" in the suffix is optional though recommended.
• Saturated 3, 4 & 5-membered nitrogen heterocycles should use respectively the traditional "iridine", "etidine" & "olidine" suffix.
• Unsaturated nitrogen 3-membered heterocycles may use the traditional "irine" suffix.
• Consistent use of "etine" and "oline" as a suffix for 4 & 5-membered unsaturated heterocycles is prevented by their former use for similar sized nitrogen heterocycles.
• Established use of oxine, azine and silane for other compounds or functions prohibits their use for pyran, pyridine and silacyclohexane respectively.
Examples of these nomenclature rules are written in blue, both in the previous diagram and that shown below. Note that when a maximally unsaturated ring includes a saturated atom, its location may be designated by a H prefix to avoid ambiguity, as in pyran and pyrrole above and several examples below. When numbering a ring with more than one heteroatom, the highest priority atom is #1 and continues in the direction that gives the next priority atom the lowest number.
There are many more concepts and tricks are used in the lecture, We hope, You all will enjoy the Lecture.
Thanks
Team IITian explains
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Bicyclic and Polycyclic compounds | Nomenclature and details | Explained by IITian | Mains, Advanced
https://youtu.be/KDZ1jGjG5IE
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